Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators

ABSTRACT

The Present invention relates to a polymerizable composition, comprising  
     a) at least one ethylenically unsaturated monomer or oligomer,  
     b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and  
     c) at least one compound of formula (I)  
                 
 
      wherein  
     n is 1 or 2  
     R 3 , R 4 , R 9 , R 10  are each independently of one another C 1 -C 18 alkyl, C 2-C   18 alkenyl or C 2 -C 18 alkinyl; or  
     R 3  and R 4  and/or R 9  and R 10  form together with the linking carbon atom a C 3 -C 12 cycloalkyl radical;  
     R 5 , R 6 , R 7 , R 8  are each independently of one another hydrogen, C 1 -C 18 alkyl, C 2 -C 18 alkenyl or C 2 -C 18 alkinyl;  
     X is —O—, —O—C(O)—, —NR 2 — or —NR 2 —C(O)—;  
     R 2  is hydrogen, C 1 -C 18 alkyl or phenyl;  
     if n is 1,  
     R 1  is C 8 -C 36 alkyl, C 8 -C 36 alkenyl or C 8 -C 36 alkinyl  
     if n is 2  
     R 1  is C 10 -C 36 alkylen, C 10 -C 36 alkenylen or C 10 -C 36 alkinylen.  
     Further objects of the present invention are a process for polymerization and the use of compounds of formula I for the polymerizabon of ethylenically unsaturated monomers.

[0001] The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer, b) a free radical source and c) a 2,2,6,6-tetraalkylpiperidine having a long chain alkyl group. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of a 2,2,6,6-tetraalkylpiperidine derivative having a long chain alkyl group for controlled polymerization.

[0002] The compounds of the present invention provide polymeric resin products having low polydispersity. The polymerization process proceeds with enhanced monomer to polymer conversion efficiency. In particular, this invention relates to stable free radical-mediated polymerization processes which provide homopolymers, random copolymers, block copolymers, multiblock copolymers, graft copolymers and the like, at enhanced rates of polymerization and enhanced monomer to polymer conversions.

[0003] Polymers or copolymers prepared by conventional free radical polymerization processes inherently have broad molecular weight distributions or polydispersities which are generally higher than the theoretical limit of 1.5-2.0. In industrial processes values higher than four are not uncommon.

[0004] Conventional radical polymerization processes pose various significant problems, such as difficulties in predicting or controlling the molecular weight, the polydispersity and the modality of the polymers produced. These prior art polymerization processes produce polymers having broad polydispersities.

[0005] Furthermore, free radical polymerization processes in bulk of the prior art are difficult to control because the polymerization reaction is strongly exothermic and an efficient heat removal in the highly viscous polymer is mostly impossible. The exothermic nature of the prior art free radical polymerization processes often severely restricts the concentration of reactants or the reactor size upon scale-up.

[0006] Due to the above mentioned uncontrollable polymerization reactions, gel formation in conventional free radical polymerization processes are also possible and cause broad molecular weight distributions and/or difficulties during filtering, drying and manipulating the product resin.

[0007] U.S. Pat. No. 4,581,429 to Solomon et al., issued Apr. 8, 1986, discloses a free radical polymerization process which controls the growth of polymer chains to produce short chain or oligomeric homopolymers and copolymers, including block and graft copolymers. The process employs an initiator having the formula (in part) R′R″N—O—X, where X is a free radical species capable of polymerizing unsaturated monomers. The reactions typically have low conversion rates. Specifically mentioned radical R′R″N—O groups are derived from 1,1,3,3-tetraethylisoindoline, 1,1,3,3-tetrapropylisoindoline, 2,2,6,6-tetramethylpiperidine, 2,2,5,5-tetramethylpyrrolidine or di-t-butylamine. However, the suggested compounds do not fulfill all requirements.

[0008] EP-A-735 052 discloses a general method for preparing thermoplastic polymers of narrow polydispersities by free radical-initiated polymerization, which comprises adding a free radical initiator (free radical source) and a stable free radical agent to the monomer compound.

[0009] This method has the disadvantage that uncontrollable recombinations of initiator radicals occur immediately after their formation, thus producing variable ratios between initiator radicals and stable free radicals. Consequenty monomer to polymer conversion may become low and/or polydispersity high.

[0010] JP 8269117, published 1996 has selected the N-oxyls of bis(2,2,6,6-tetramethyl-4-piperidyl)sebacic acid ester and tetrakis (2,2,6,6-tetramethyl-4-pipeddyl)1,2,3,4-butanetetracarboxylate as being particularly useful in controlled polymerization reactions.

[0011] Surprisingly it has now been found that 2,2,6,6-tetraalkylpiperidine derivatives having a long chain alkyl or alkylene group in 4 position attached to the piperidine ring are excellent regulators in such systems.

[0012] Monomer to polymer conversion is higher as known from prior art polymerizations and polydispersity of the polymers produced is surprisingly low, whereas reaction times are short even at relatively low temperatures, making the polymerization process particularly suitable for industrial applications.

[0013] The polymerization processes and resin products of the present invention can be used for a wide range of purposes, for example for pipes, profiles, sheets, cable insulations, sports equipment, garden furniture, films, structural parts, parts of vehicles and machines, and containers of any type, for example bottles, foamed materials, such as insulation panels or packaging material. The polymerization processes are useful for the preparation of block copolymers which are useful as compatibilizing agents or impact modifiers for polymer blends, or dispersing agents for coating systems or for the preparation of narrow molecular weight resins or oligomers for use in coating technologies and thermoplastic films or as toner resins and liquid immersion development ink resins or ink additives used for electrophotographic imaging processes.

[0014] The polymers obtainable according to this invention can be brought into the desired shape in known manner. Such processes are, for example grinding, calendering, extruding, injection moulding, blow moulding, sintering and spinning.

[0015] The resulting (co)polymers are of high purity, therefore not requiring any further purification.

[0016] One object of the present invention is to provide a polymerizable composition, comprising

[0017] a) at least one ethylenically unsaturated monomer or oligomer,

[0018] b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and

[0019] c) at least one compound of formula (I)

[0020]  wherein

[0021] n is 1 or 2

[0022] R₃, R₄, R₉, R₁₀ are each independently of one another C₁-C₁₈alkyl, C₂-C₁₈alkenyl or C2-C₁₈alkinyl; or

[0023] R₃ and R₄ and/or R₉ and R₁₀ form together with the linking carbon atom a C₃-C₁₂cycloalkyl radical;

[0024] R₅, R₆, R₇, R₈ are each independently of one another hydrogen, C₁-C₁₈alkyl, C₂-C₁₈alkenyl or C₂-C₁₈alkinyl;

[0025] X is —O—, —O—C(O)—, —NR₂— or —NR₂—C(O)—;

[0026] R₂ is hydrogen, C₁-C₁₈alkyl or phenyl;

[0027] if n is 1,

[0028] R₁ is C₈-C₃₆alkyl, C₈-C₃₆alkenyl or C₈-C₃₆alkinyl

[0029] if n is 2

[0030] R₁ is C₁₀-C₃₆alkylen, C₁₀-C₃₆alkenylen or C₁₀-C₃₆alkinylen.

[0031] The alkyl radicals may be linear or branched. Examples of alkyl containing 1 to 18 carbon atoms are methyl, ethyl, propyl, isopropyl, butyl, 2-butyl, isobutyl, t-butyl, pentyl, 2-pentyl, hexyl, heptyl, octyl, 2-ethylhexyl, t-octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl and octadecyl.

[0032] Examples for alkyl containing up to 36 carbon atoms are eicosyl, docosyl, pentacosyl, hexacosyl, heptacosyl or octacosyl.

[0033] The alkenyl radicals may be linear or branched. Examples of C₈-C₃₆alkenyl are octenyl, undecenyl, octadecenyl, eicosenyl, pentacosenyl or octacosenyl.

[0034] Examples of C₈-C₃₆alkinyl are 5-undecinyl, 6-octadecinyl, eicosinyl, pentacosinyl or octacosinyl. The alkinyl radicals may be linear or branched.

[0035] Typical alkylen groups are decylen, eicosylen, pentacosylen

[0036] Preferably R₃, R₄, R₉, R₁₀ are methyl groups and R₅, R₆, R₇, R₈ are hydrogen.

[0037] Preferably X is —O— or —O—C(O)—, more preferably X is —O—C(O)—.

[0038] Preferably n is 1 and R₁ is C₈-C₂₅alkyl, more preferably C₁₁-C₂₅alkyl and most preferably C₁₅-C₂₅alkyl.

[0039] A particularly preferred group of compounds are those of formula

[0040] Another preferred group of compounds is, wherein n is 2 and R₁ is C₁₂-C₂₄alkylen.

[0041] R₂ is preferably hydrogen or C₁-C₄alkyl.

[0042] When the compounds of formula (I) are prepared from commercial grade starting materials the substituent R₁ may often be a mixture of alkyl or alkylene chains of different lengths, centered around a main component.

[0043] Preferably the ethylenically unsaturated monomer or oligomer is selected from the group consisting of styrene, substituted styrene, conjugated dienes, acrolein, acrylonitril, vinyl acetate, (alkyl)acrylic acidanhydrides, (alkyl)acrylic acid salts, (alkyl)acrylic esters or (alkyl)acrylamides.

[0044] More preferably the ethylenically unsaturated monomer is styrene, a-methyl styrene, p-methyl styrene, 1,3-dienes or a compound of formula CH2═C(R_(a))—(C═Z)—R_(b), wherein R_(a) is hydrogen or C₁-C₄alkyl, R_(b) is NH₂, OMe, glycidyl, unsubstituted C₁-C₁₈alkoxy or hydroxy-substituted C₁-C₁₈alkoxy, unsubstituted C₁-C₁₈alkylamino, di(C₁-C₁₈alkyl)amino, hydroxy-substituted C₁-C₁₈alkylamino or hydroxy-substituted di(C₁-C₁₈alkyl)amino. Z is oxygen or sulfur and Me is an alkali metal cation.

[0045] Most preferably the ethylenically unsaturated monomer is styrene, α-methyl styrene, p-methyl styrene, butadiene, isoprene.

[0046] Preferably the compound of formula (I) or a mixture thereof is present in an amount of from 0.001 mol-% to 30 mol-%, more preferred in an amount of from 0.002 mol-% to 5 mol-% and most preferred in an amount of from 0.005 mol-% to 2 mol-% based on the monomer or monomer mixture.

[0047] The molar ratio between free radical source b) and the nitroxyl compound of formula I is preferably from 20:1-1:2, more preferably from 10:1-1:1.5 and most preferably from 2:1-1:1.4. Particularly preferred is a molar ratio of 1:1.3.

[0048] When monomer mixtures are used mol % is based on an average molecular weight of the mixture.

[0049] A further object of the present invention is a process for preparing an oligomer, a cooligomer, a polymer or a copolymer (block or random) by free radical polymerization of at least one ethylenically unsaturated monomer or oligomer, which comprises heating the monomer or monomers/oligomers in the presence of a free radical source and a compound of formula (I) and polymerizing the ethylenically unsaturated monomer or oligomer.

[0050] The definitions and preferences given for the composition apply also for the process for preparing an oligomer, a cooligomer, a polymer or a copolymer.

[0051] The polymerization reaction temperature is kept relatively constant throughout the heating step by providing an adjustable external heat source and the temperature is from about 60° C. to 220° C. preferably between 100° C and 180° C. and optimally between 120° C. and 140° C. Reactions performed above 160° C. tend to result in a broadening of the polydispersity.

[0052] A reaction volume may be selected for any size that enables simple adding, mixing, reacting and isolating the product on an economic or convenient scale.

[0053] Preferably the free radicals from the free radical source are generated thermally. Therefore the radical formation depends on the decomposition temperature of the radical generator. Peroxides can be used within a temperature range from 60° C. to 180° C. more preferably from 110° C. to 180° C. Azo compounds have lower decomposition temperatures and can therefore be used within 40° C. to 140° C. more preferably from 60° C. to 120° C.

[0054] Yet another object of the present invention is the use of a compound of formula (I) together with a free radical source for the controlled polymerization of ethylenically unsaturated monomers or oligomers.

[0055] The production of C-centered radicals is described, inter alia, in Houben Weyl, Methoden der Organischen Chemie, Vol. E 19a, pages 60-147. These methods can be applied in general analogy.

[0056] Examples of free radical sources suitable in the present invention are derived from peroxides, hydroperoxides or azo compounds

[0057] Examples for free radical sources are 2,2′-azobisisobutyronitrile, 2,2′-azobis(2-methylbutyronitrile), 2,2′-azobis(2,4-dimethylvaleronitrile), 2,2′-azobis(4-methoxy-2,4-dimethylvaleronitrile), 1,1′-azobis(1-cyclohexanecarbonitrile), 2,2′-azobis(isobutyramide) dihydrate, 2-phenylazo-2,4-dimethyl-4-methoxyvaleronitrile, dimethyl-2,2′-azobisisobutyrate, 2-(carbamoylazo)isobutyronitrile, 2,2′-azobis(2,4,4trimethylpentane), 2,2′-azobis(2-methylpropane), 2,2′-azobis(N,N′-dimethyleneisobutyramidine), free base or hydrochloride, 2,2′-azobis(2-amidinopropane), free base or hydrochloride, 2,2′-azobis{2-methyl-N-[1,1-bis(hydroxymethyl)ethyl]propionamide} or 2,2′-azobis(2-methyl-N-[1, 1-bis(hydroxymethyl)-2-hydroxyethyl]propionamide, methylethylketonperoxide, 2,5-dimethyl-2,5-di-tert.-butylperoxyhexane, 2,5-dimethyl-2,5-di-tert.-butylperoxyhexyne, di-tert.-butyl-peroxide, di-tert.-butylperoxyisopropylbenzene, tert.-butyl-3-isopropenylcumeneperoxide, di-(1-hydroxycyclohexyl)peroxide, dibenzylperoxid), diisopropylperoxydicarbonate, bis-(4-tert.-butylcyclohexyl)peroxidicarbonate, tert.-butylperoxybenzoate or hydrogenperoxide.

[0058] Preferred radical sources are 2,2′-azobisisobutyronitrile, 1,1′-azobis(1-cyclohexanecarbonitrile), 2,2′-azobisisobutylacetate. 5,5′-azobis-(5-ethyl-1,3-dioxane), dibenzoylperoxide, dicumylperoxide, di-tert.butylperoxide, di-laurylperoxide, cumylhydroperoxide and hydrogenperoxide and mixtures thereof.

[0059] Preferably the radical source is present in an amount of from 0.001 to 25 mol %, more preferably from 0.002 to 10 mol % and most preferred from 0.005 to 2 mol %, based on the monomer used.

[0060] The compounds of formula (I) and their precursors are known and their preparation is described for example in U.S. Pat. Nos. 5,654,434 and 5,204,473.

[0061] Suitable monomers are those mentioned above. The polymers formed by the present process may be isolated prior to a next reaction step or may be used without isolation, and a second monomer is added to the reaction mixture of the first step, which leads to block copolymers.

[0062] Block copolymers are, for example, block copolymers of polystyrene and poly-1,3-dienes (e.g. Poly(styrene-co-butadiene) or Poly(styrene-co-butadiene-co-styrene)) or polystyrene and polyacrylates (e.g. Poly(styrene-co-acrylate) or Poly(styrene-co-acrylatestyrene). They are useful as polymers in applications for pipes, profiles, sheets, cable insulations, sports equipment, garden furniture, films, structural parts, parts of vehicles and machines, and containers of any type, for example bottles, foamed materials, such as insulation panels or packaging material. They can also be used as impact modifiers, adhesives, compatibilizers for polymer blends or as polymer toughening agents. Block copolymers of styrene, (meth)acrylates and/or acrylonitrile are useful plastics, elastomers and adhesives.

[0063] Furthermore, block copolymers of this invention, wherein the blocks alternate between polar monomers and non-polar monomers, are useful in many applications as amphiphilic surfactants or dispersants for preparing highly uniform polymer blends.

[0064] The (co)polymers of the present invention may have a number average molecular weight from 1 000 to 500 000 g/mol, preferably from 2 000 to 250 000 g/mol and, more preferably, from 5 000 to 150 000 g/mol. The number average molecular weight may be determined by size exclusion chromatography (SEC), gel permeation chromatography (GPC), matrix assisted laser desorption/ionization mass spectrometry (MALDI-MS) or, if the initiator carries a group which can be easily distinguished from the monomer(s), by NMR spectroscopy or other conventional methods.

[0065] The (co)polymers of the present invention typically have a low polydispersity. Preferably the polydispersity is from 1.1 to 2.2, more preferably from 1.1 to 1.9 and most preferably from 1.2 to 1.8.

[0066] The present invention also encompasses in the synthesis novel block, multi-block, star, gradient, random, hyperbranched and dendritic copolymers, as well as graft or copolymers.

[0067] The polymers prepared by the present invention are useful for following applications:

[0068] pipes, profiles, sheets, cable insulations, sports equipment, garden furniture, films, structural parts, parts of vehicles and machines, and containers of any type, for example bottles, foamed materials, such as insulation panels or packaging material, impact modifiers, compatibilizers for polymer blends, polymer toughening agents, adhesives, detergents, dispersants, emulsifiers, surfactants, defoamers, adhesion promoters, corrosion inhibitors, viscosity improvers, lubricants, rheology modifiers, thickeners, crosslinkers, paper treatment, water treatment, electronic materials, paints, coatings, photography, ink materials, imaging materials, superabsorbants, cosmetics, hair products, preservatives, biocide materials or modifiers for asphalt, leather, textiles, ceramics and wood.

[0069] Because the present polymerizaton is a “living” polymerization, it can be started and stopped practically at will. Furthermore, the polymer product retains the functional alkoxyamine group allowing a continuation of the polymerization in a living matter. Thus, in one embodiment of this invention, once the first monomer is consumed in the initial polymerizing step a second monomer can then be added to form a second block on the growing polymer chain in a second polymerization step. Therefore it is possible to carry out additional polymerizations with the same or different monomer(s) to prepare multi-block copolymers.

[0070] Furthermore, since this is a radical polymerization, blocks can be prepared in essentially any order. One is not necessarily restricted to preparing block copolymers where the sequential polymerizing steps must flow from the least stabilized polymer intermediate to the most stabilized polymer intermediate, such as is the case in ionic polymerization. Thus it is possible to prepare a multi-block copolymer in which a styrene or 1,3-diene block is prepared first, then a polyacrylonitrile or a poly(meth)acrylate block is attached thereto, and so on. Furthermore, there is no linking group required for joining the different blocks of the present block copolymer. One can simply add successive monomers to form successive blocks. A plurality of specifically designed polymers and copolymers are accessible by the present invention, such as star and graft (co)polymers as described, inter alia, by C. J. Hawker in Angew. Chemie, 1995, 107, pages 1623-1627, dendrimers as described by K. Matyaszewski et al. in Macromolecules 1996, 29, pages 4167-4171, graft (co)polymers as described by C. J. Hawker et al. in Macromol. Chem. Phys. 1997, 198, 155-166, random copolymers as described by C. J. Hawker in Macromolecules 1996, 29, 2686-2688, or diblock and triblock copolymers as described by N. A. Listigovers in Macromolecules 1996, 29, 8992-8993.

[0071] The process may be carried out in the presence of an organic solvent or in the presence of water or in mixtures of organic solvents and water. Additional cosolvents or surfactants, such as glycols or ammonium salts of fatty acids, may be present. Other suitable cosolvents are described hereinafter.

[0072] Preferred processes use as little solvents as possible. In the reaction mixture it is preferred to use more than 30% by weight of monomer, radical source and regulator, particularly preferably more than 50% and most preferrably more than 80%.

[0073] Most preferred processes are bulk polymerizations without any solvent.

[0074] If organic solvents are used, suitable solvents or mixtures of solvents are typically pure alkanes (hexane, heptane, octane, isooctane), hydrocarbons (benzene, toluene, xylene), halogenated hydrocarbons (chlorobenzene), alkanols (methanol, ethanol, ethylene glycol, ethylene glycol monomethyl ether), esters (ethyl acetate, propyl, butyl or hexyl acetate) and ethers (diethyl ether, dibutyl ether, ethylene glycol dimethyl ether), or mixtures thereof.

[0075] The following examples illustrate the invention.

[0076] Preparation of Compound 101

[0077] To a solution of 2,2,6,6-tetramethylpiperidin-4-hydroxy-1-N-oxyl (43.1 g) in toluene (60 g) tetrabutylammonium bromide (2.7 g) is added, followed by a solution of sodium hydroxyde (33 g) in water (33 g). The mixture is heated to 55° C. To the well stirred mixture 1 octyl bromide (96.6 g) is added over a period of one hour. The reaction mixture is stirred over night and then cooled down to room temperature. The mixture is washed with water and the organic phase dried over sodium sulfate. After evaporation of the solvent a red liquid, which is further purified by column chromatography (silica gel; petrol ether/acetic ester=9/1) is obtained. The red oil corresponds to the formula

[0078] Preparation of Compound 107

[0079] To an agitated ice cold solution of 2,2,6,6-tetramethylpiperidin-4-hydroxy-1-N-oxyl (98.2 g) and triethylamine (69.3 g) in toluene (220 g) a solution of stearic acid chloride (205.4 g) in toluene (220 g) is added within one hour. After completed addition the temperature is raised to room temperature and agitation continued for another 18 h. The suspension is extracted with water several times. The organic phase is dried over magnesium sulfate, filtered and evaporated to dryness. The residue is dissolved in petrolether/acetic acid ester (9/1) and filtered over a silicagel column. After evaporation of the solvents, the residue is dried under high vacuum at 60° C. Compound 107 is obtained as a red brownish solid with a melting point of 34-35° C.:

[0080] Preparation of Compound 108

[0081] Acylation

[0082] To an agitated solution of 2,2,6,6-tetramethyl-4-amino-piperidine (71.2 g) in toluene (430 g) triethylamine (60.7 g) and 4-dimethylamino-pyridine (0.6 g) are added at room temperature. Within 30 min a solution of laurinic acid chloride (120.3 g) in toluene (87 g) is slowly added and the reaction temperature maintained below 40° C. After complete addition the temperature is raised to 100° C. and agitation continued for 18 h. After cooling to room temperature the suspension is filtered and the residue taken up with methylenchloride (660 g) and washed several times with a saturated aqueous solution of sodium bicarbonate. The organic solution is dried over magnesium sulfate and evaporated to dryness. A white solid of formula

[0083] is obtained melting at >250° C.

[0084] Oxidation

[0085] To an agitated ice cold mixture of the above amide (101.6 g) in tetrahydrofurane (250 g) a solution of m-chloroperbenzoic acid (70%, 125.8 g) in tetrahydrofurane (460 g) is added within one hour. After complete addition agitation is continued for 17 h at room temperature. The red solution is diluted with hexane (600 g) and the mixture extracted with several portions of a 1 M aqueous solution of sodium bicarbonate and afterwards with a saturated solution of sodium chloride. The organic phase is dried over sodium sulfate and evaporated to dryness. The residue is further purified by column chromatography (silica gel; hexane/acetic acid ethylester=1:1). Compound 108 is obtained as a red solid with a melting point of 48-50° C.

[0086] Compounds are prepared are listed in Table 1 TABLE 1 Compound No. Structure Remarks 101

red oil 102

prepared in analogy to compound 101; mp.41-44° C. 103

prepared in analogy to compound 107; red oil 104

prepared in analogy to compound 107; red oil 105

prepared in analogy to compound 107; mp. 35-36° C. 106

prepared in analogy to compound 107; red oil 107

mp. 34-35° C. 108

mp. 48-50° C. 109

prepared in analogy to compound 108; mp. 41-43° C. 110

prepared in analogy to compound 108, mp. 49-52° C. 111

prepared in analogy to compound 107; mp. 33.5° C. 112

prepared in analogy to compound 108; mp. 54° C. 113

prepared in analogy to compound 108; red oil 114

prepared in analogy to compound 107; mp. 54-55° C.

[0087] in an evacuated Schlenk reactor, purged with argon, the amount of initiator and stable nitroxyl radical given in Table 2 are added to 50 ml styrene under argon atmosphere. Dissolved oxygen is removed in two freeze thaw cycles (liquid nitrogen). The reaction mixture is stirred and heated under argon atmosphere to 130° C. for 6 hours. Remaining monomer is removed at 60° C. under vacuum. The residue is dried in a first step under second step under normal pressure at 70° C. until constant weight is achieved.

[0088] Molecular weights and molecular weight distributions are determined by gel permeation chromatography (GPC).

[0089] The results shown in Table 2 TABLE 2 Conc. % on BPO % on Conversion M_(w)/ No. NO-radical styrene styrene (%) M_(n) M_(w) M_(n) V1 TEMPO   1 mol %  0.77 mol % 28 3700 4800 1.29 V2 HO-TEMPO   1 mol %  0.77 mol % 17 2100 2600 1.26 V3 Benzoyl-   1 mol %  0.77 mol % 39 4800 6000 1.25 TEMPO Ex. 1 Compound   1 mol %  0.77 mol % 63 9000 11200 1.25 107 Ex. 2 Compound  0.1 mol %  0.077 mol % 75 54000 77300 1.43 107 Ex. 3 Compound 0.01 mol % 0.0077 mol % 72 148300 272100 1.83 107 Ex. 4 Compound 0.05 mol % 0.0385 mol % 73 78300 114300 1.46 107 Ex. 5 Compound  0.5 mol %  0.385 mol % 61 16300 20500 1.26 107 Ex. 6 Compound 0.01 mol % 0.0077 mol % 72 153000 254000 1.65 104 Ex. 7 Compound 0.05 mol % 0.0385 mol % 71 77200 110100 1.43 104 Ex. 8 Compound  0.5 mol %  0.385 mol % 40 10200 12100 1.20 104 Ex. 9 Compound   1 mol %  0.77 mol % 49 7900 9200 1.16 104 Ex. 10 Compound 0.1 mol % 0.077 mol % 68 51900 76300 1.47 103 Ex. 11 Compound   1 mol % 0.77 mol % 66 10200 13100 1.28 103 

1. A polymerizable composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and c) at least one compound of formula (I)

 wherein R₃, R₄, R₉, R₁₀ are each independently of one another C₁-C₁₈alkyl, C₂-C₁₈alkenyl or C2-C₁₈alkinyl; or R₃ and R₄ and/or R₉ and R₁₀ form together with the linking carbon atom a C₃-C₁₂cycloalkyl radical; R₅, R₆, R₇, R₈ are each independently of one another hydrogen, C₁-C₁₈alkyl, C₂-C₁₈alkenyl or C₂-C₁₈alkinyl; X is —O—, —O—C(O)—, —NR₂— or —NR₂—C(O)—; R₂ is hydrogen, C₁-C₁₈alkyl or phenyl; if n is 1, R₁ is C₈-C₃₆alkyl, C₈-C₃₆alkenyl or C₈-C₃₆alkinyl if n is 2 R₁ is C₁₀-C₃₆alkylen, C₁-C₃₆alkenylen or C₁₀-C₃₆ alkinylen.
 2. A composition according to claim 1, wherein R₃, R₄, R₉ and R₁₀ are each methyl and R₅, R₆, R₇ and R₈ are each hydrogen.
 3. A composition according to claim 1 wherein X is O or —O—C(O)—
 4. A composition according to claim 1 wherein n is 1 and RI is C₈-C₂₅alkyl
 5. A composition according to claim 1 wherein n is 2 and R₁ is C₁₂-C₂₄alkylen.
 6. A composition according to claim 1, wherein the ethylenically unsaturated monomer or oligomer is selected from the group consisting of styrene, substituted styrene, conjugated dienes, acrolein, acrylonitril, vinyl acetate, (alkyl)acrylic acidanhydrides, (alkyl)acrylic acid salts, (alkyl)acrylic esters or (alkyl)acrylamides.
 7. A composition according to claim 6 wherein the ethylenically unsaturated monomer is styrene, a-methyl styrene, p-methyl styrene, 1,3-dienes or a compound of formula CH₂═C(R_(a))—(C═Z)—R_(b), wherein R_(a) is hydrogen or C₁-C₄alkyl, R_(b) is NH₂, OMe, glycidyl, unsubstituted C₁-C₁₈alkoxy or hydroxy-substituted C₁-C₁₈alkoxy, unsubstituted C₁-C₁₈alkylamino, di(C₁-C₁₈alkyl)amino, hydroxy-substituted C₁-C₁₈alkylamino or hydroxy-substituted di(C₁-C₁₈alkyl)amino; Z is oxygen or sulfur, and Me is an alkali metal cation.
 8. A composition according to claim 6, wherein the ethylenically unsaturated monomer is styrene, α-methyl styrene, p-methyl styrene, butadiene or isoprene.
 9. A composition according to claim 1, wherein the compound of formula (I) or a mixture thereof is present in an amount of from 0.001 mol-% to 30 mol-%, based on the monomer or monomer mixture.
 10. A process for preparing an oligomer, a cooligomer, a polymer or a copolymer (block or random) by free radical polymerization of at least one ethylenically unsaturated monomer or oligomer, which comprises heating the monomer or monomers/oligomers in the presence of a free radical source and a compound of formula I according to claim 1 and polymerizing the ethylenically unsaturated monomer or oligomer.
 11. A process in accordance with claim 10, wherein the free radicals from the free radical source are generated at a temperature from 60° C. to 220° C.
 12. A process according to claim 11, wherein the free radicals from the free radical source are generated at a temperature from 60° C. to 180° C.
 13. Use of a compound of formula (I) according to claim 1 together with a free radical source for the controlled polymerization of ethylenically unsaturated monomers or oligomers. 